Address
Southern Methodist University
Department of Chemistry
3215 Daniel Avenue
Fondren Science Building
Dallas, TX 75275, USA
Phone: 214-768-7879
Email: yborguet@smu.edu
Hometown
Saint-Remy, Liège, Belgium
Education
Ph.D., Chemistry, 2011
University of Liège
Liège, Belgium
Thesis: “Design and Synthesis of New Ruthenium Catalysts for the Formation of C—C bonds”
Master of Advanced Studies, 2007
University of Liège
Liège, Belgium
Thesis: “Microwave-Assisted Atom Transfer Radical Addition and Polymerization Catalyzed by Ruthenium Complexes”
Master Thesis, Chemistry, 2005
University of Liège
Liège, Belgium
Thesis: “Catalytic activity of Mono and Homo-Bimetallic Ruthenium complexes for the ATRP of Styrene and Methyl Methacrylate”
Affiliations
American Chemical Society
Société Royale de Chimie Belge
IUPAC
Professional Experience
2012-pres Postdoctoral Fellow, Southern Methodist University.
2005-2011 Teaching Assistant, Department of Chemistry, University of Liège.
2004-2005 Student Instructor, Department of Chemistry, University of Liège.
Publications
Journal Articles (peer-reviewed)
- “Controlled Radical Polymerization of a Styrenic Sulfonium Monomer and Post-Polymerization Modifications,” Polym. Chem., 2013, 4, in press, Y. P. Borguet, N. V. Tsarevsky
- "Assessing the ligand properties of 1,3-dimesitylbenzimidazol-2-ylidene in ruthenium-catalyzed olefin metathesis," Dalton Trans., 2012, in press, Y. Borguet, G. Zaragoza, A. Demonceau, L. Delaude
- "Low-Catalyst Concentration Atom Transfer Radical Polymerization of a Phosphonium Salt-Type Monomer," Polym. Chem., 2012, 3, 2487-2494, Y. Borguet, N.V. Tsarevsky
- "An Unexpected Synthesis of Dihydrophenazines en Route to Benzimidazolium Salts," Adv. Synth. Catal., 2012, 354, 1356-1362, Y. Borguet, G. Zaragoza, A. Demonceau, L. Delaude
- "Olefin Metathesis as Key Step in the Synthesis of Bioactive Compounds: Challenges in the Total Synthesis of (–)-Kendomycin," Curr. Org. Synth., 2012, 9, 397-405, D. Bicchielli, Y. Borguet, L. Delaude, A. Demonceau, I. Dragutan, V. Dragutan, M. Hans, C. Jossifov, F. Nicks, Q. Willem
- "Synthesis and Catalytic Evaluation in Olefin Metathesis of a Second-Generation Homobimetallic Ruthenium-Arene Complex Bearing a Vinylidene Ligand," Organometallics, 2011, 30, 2730-2738, Y. Borguet, X. Sauvage, G. Zaragoza, A. Demonceau, L. Delaude
- "Tandem Catalysis of Ring-Closing Metathesis/Atom Transfer Radical Reactions with Homobimetallic Ruthenium-Arene Complexes," Beilstein J. Org. Chem., 2010, 6, 1167-1173, Y. Borguet, X. Sauvage, G. Zaragoza, A. Demonceau, L. Delaude
- "Homobimetallic Ruthenium-Arene Complexes Bearing Vinylidene Ligands: Synthesis, Characterization, and Catalytic Application in Olefin Metathesis," Organometallics, 2010, 29, 6675-6686, Y. Borguet, X. Sauvage, G. Zaragoza, A. Demonceau, L. Delaude
- "Homobimetallic Ruthenium-Ethylene, Vinylidene, Allenylidene, and Indenylidene Catalysts for Olefin Metathesis," Macromol. Symp., 2010, 293, 24-27, X. Sauvage, Y. Borguet, A. Demonceau, L. Delaude
- "Microwave-Assisted Ruthenium-Catalysed Reactions," Aust. J. Chem., 2009, 62, 184-207, F. Nicks, Y. Borguet, S. Delfosse, D. Bicchielli, L. Delaude, X. Sauvage, A. Demonceau
- "Homobimetallic Ruthenium Vinylidene, Allenylidene, and Indenylidene Complexes: Synthesis, Characterisation, and Catalytic Studies," Adv. Synth. Catal., 2009, 351, 441-455, X. Sauvage, Y. Borguet, G. Zaragoza, A. Demonceau, L. Delaude
- "Microwave-Enhanced Ruthenium Catalysed Atom Transfer Radical Additions," Tetrahedron Lett., 2007, 48, 6334-6338, Y. Borguet, A. Richel, S. Delfosse, A. Leclerc, L. Delaude, A. Demonceau
- "Single Mode Microwave Assisted Atom Transfer Radical Polymerisation Catalysed by [RuCl2(p-cymene)(PCy3)]," Macromol. Rapid Commun., 2007, 28, 492-503, S. Delfosse, Y. Borguet, L. Delaude, A. Demonceau
- "Homobimetallic Ruthenium-N-Heterocyclic Carbene Complexes: Synthesis, Characterisation, and Catalytic Applications," Adv. Synth. Catal., 2007, 349, 255-265, X. Sauvage, Y. Borguet, A.F. Noels, L. Delaude, A. Demonceau
Book Chapters (peer-reviewed)
- Homobimetallic Ethylene- and Vinylidene-Ruthenium Complexes for ATRP, ACS Symposium Series, Vol. 1100, K. Matyjaszewski, B.S. Sumerlin, N.V. Tsarevsky, Eds., Progress in Controlled Radical Polymerization: Mechanisms and Techniques, Washington DC, 2012, 115-132, Y. Borguet, L. Delaude, A. Demonceau
- Microwave-Assisted Olefin Metathesis, Green Metathesis Chemistry, V. Dragutan, A. Demonceau, I. Dragutan, E.S. Finkelshtein, Eds., NATO Science for Peace and Security Series-A: Chemistry and Biology, Springer, Dordrecht, 2010, 327-358, F. Nicks, Y. Borguet, X. Sauvage, D. Bicchielli, S. Delfosse, L. Delaude, A. Demonceau
- Recent Applications of Alkene Metathesis in Fine Chemical Synthesis, Green Metathesis Chemistry, V. Dragutan, A. Demonceau, I. Dragutan, E.S. Finkelshtein, Eds., NATO Science for Peace and Security Series-A: Chemistry and Biology, Springer, Dordrecht, 2010, 207-274, D. Bicchielli, Y. Borguet, L. Delaude, A. Demonceau, I. Dragutan, V. Dragutan, C. Jossifov, R. Kalinova, F. Nicks, X. Sauvage
- Mono- and Bimetallic Ruthenium—Arene Catalysts for Olefin Metathesis: A Survey, Green Metathesis Chemistry, V. Dragutan, A. Demonceau, I. Dragutan, E.S. Finkelshtein, Eds., NATO Science for Peace and Security Series-A: Chemistry and Biology, Springer, Dordrecht, 2010, 89-100, Y. Borguet, X. Sauvage, A. Demonceau, L. Delaude
- ATRP of Methacrylates Catalysed by Homo- and Heterobimetallic Ruthenium Complexes, ACS Symposium Series, Vol. 1023, K. Matyjaszewski, Ed., Controlled/Living Radical Polymerization: Progress in ATRP, American Chemical Society, Washington DC, 2009, 97-114, Y. Borguet, X. Sauvage, D. Bicchielli, S. Delfosse, L. Delaude, A. Demonceau, L. Bareille, P. Le Gendre, C. Moïse
Preprints and other non-peer-reviewed articles
- "ATRP of Methyl methacrylate and Styrene Catalysed by Homobimetallic Ruthenium-Vinylidene Complexes," Polym. Prepr., 2011, 52, 540-541, Y. Borguet, M.Z. Aldin, D. Bicchielli, L. Delaude, A. Demonceau
- "ATRP of Methyl Methacrylate and Styrene Catalysed by Homobimetallic Ruthenium-Vinylidene Complexes," Polym. Prepr., 2008, 49 (2), 22-23, D. Bichielli, Y. Borguet, X. Sauvage, L. Delaude, A. Demonceau
- "ATRP Catalysed by Novel Homo- and Heterobimetallic Ruthenium Complexes," Polym. Prepr., 2008, 49 (2), 24-25, Y. Borguet, S. Delfosse, X. Sauvage, A. Demonceau, L. Delaude, L. Bareille, P. Le Gendre, C. Moïse
- "Controlled Radical Polymerisation of Vinyl Monomers Catalysed by Ruthenium N-Heterocyclic Carbene Complexes," Polym. Prepr., 2005, 46 (2), 191-192, S. Delfosse, A. Richel, Y. Borguet, L. Delaude, A. Demonceau, A.F. Noels
Research Presentations
Seminars
- An Unexpected Synthesis of Dihydrophenazines en Route to Second-Generation Olefin Metathesis Catalysts, 14th Sigma-Aldrich Organic Synthesis Meeting (December 2-3, 2010, Spa, Belgium), Y. Borguet, L. Delaude, A. Demonceau
- The First Synthesis of 1,3-Dimesitylbenzimidazolium Salts. Synthesis of the Corresponding Grubbs Complex and Application in Olefin Metathesis, ASMOS-VI (November 3-5, 2010, Corcelles-les-Monts, France), Y. Borguet, L. Delaude, A. Demonceau
- The First Synthesis of 1,3-Dimesitylbenzimidazolium Salts. Synthesis of the Corresponding Grubbs Complex and Application in Olefin Metathesis, Réunion du Département de Chimie (September 7, 2010, Liège, Belgium), Y. Borguet, L. Delaude, A. Demonceau
- Homobimetallic Ruthenium-Arene Complexes Bearing Vinylidene Ligands: Synthesis, Characterisation and Application in Olefin Metathesis, NATO Advanced Study Institute (July 20-29, 2008, Bucharest, Romania), Y. Borguet, X. Sauvage, L. Delaude, A. Demonceau
Posters
- Synthesis and Catalytic Evaluation of Second-Generation Ruthenium Complexes Bearing Benzimidazol-2-ylidene Ligands, 19th International Symposium on Olefin Metathesis (July 10-15, 2011, Rennes, France), Y. Borguet, G. Zaragoza, L. Delaude, A. Demonceau
- The First Synthesis of 1,3-Dimesitylbenzimidazolium Salts. Synthesis of the Corresponding Grubbs Complex and Application in Olefin Metathesis, 17th International Symposium on Homogeneous Catalysis (July 4-9, 2010, Poznan, Poland), Y. Borguet, G. Zaragoza, A. Demonceau, L. Delaude
- Ruthenium-Catalyzed Tandem Ring Closing Metathesis (RCM) – Atom Transfer Radical Cyclisation (ATRC) Sequences, 13th Sigma-Aldrich Organic Synthesis Meeting (December 3-4, 2009, Spa, Belgium), Y. Borguet, X. Sauvage, L. Delaude, A. Demonceau
- Homobimetallic Ruthenium Vinylidene, Allenylidene, and Indenylidene Complexes: Synthesis, Characterisation, and Catalytic Activity, 12th Sigma-Aldrich Organic Synthesis Meeting (December 4-5, 2008, Spa, Belgium), Y. Borguet, X. Sauvage, A. Demonceau, L. Delaude
- Homobimetallic Ruthenium-Arene Complexes Bearing Vinylidene Ligands: Synthesis, Characterisation and Application in Olefin Metathesis, Journée de l’EDT CHIM, (April 11, 2008, Liège, Belgium), Y. Borguet, X. Sauvage, L. Delaude, A. Demonceau
- Homobimetallic Ruthenium-Arene Complexes Bearing Vinylidene Ligands: Synthesis, Characterisation and Application in Olefin Metathesis, 11th Sigma-Aldrich Organic Synthesis Meeting (December 6-7, 2007, Spa, Belgium), Y. Borguet, X. Sauvage, L. Delaude, A. Demonceau
- Homobimetallic Ruthenium-N-Heterocyclic Carbene Complexes : Synthesis, Characterisation, and Application in Catalysis, Polymers : Last Achievements and Prospects (August 31, 2007, Liège, Belgium), Y. Borguet, X. Sauvage, L. Delaude, A.F. Noels, A. Demonceau
- Complexes Homobimétalliques de Ruthénium Porteurs de Ligands Carbéniques N-Hétérocyclique, Synthèse, Caractérisation et Applications Catalytiques, GECOM-CONCOORD 2007 (May 20-25, 2007, Plancoët, France), Y. Borguet, X. Sauvage, L. Delaude, A. Demonceau
- Application of New Homobimetallic Ruthenium-N-Heterocyclic Carbene Complexes in Atom Transfer Radical Reactions, 10th Sigma-Aldrich Organic Synthesis Meeting (December 7-8, 2006, Spa, Belgium), Y. Borguet, X. Sauvage, L. Delaude, A. Demonceau
- Olefin Cyclopropanation and Kharasch Addition Reactions Catalysed by Copper Diiminophosphorane Complexes, 9th Sigma-Aldrich Organic Synthesis Meeting (December 1-2, 2005, Spa, Belgium), Y. Borguet, S. Delfosse, L. Beaufort, A. Demonceau, A.F. Noels