Here is scenario in which Samsung wins 58 additional games (101 total) but does not finish in first place.

Here are the final standings in the scenario:
            Team	W	L	D	PCT	GB
          Hanwha	101	41	2	0.7113	0.0
         Samsung	101	42	1	0.7063	0.5
             KIA	81	58	5	0.5827	18.5
              KT	76	63	5	0.5468	23.5
          Doosan	74	65	5	0.5324	25.5
          Kiwoom	60	81	3	0.4255	40.5
              LG	59	81	4	0.4214	41.0
           Lotte	54	85	5	0.3885	45.5
             SSG	49	90	5	0.3525	50.5
              NC	45	94	5	0.3237	54.5

To construct the scenario, we start with the current standings:
            Team	W	L	D	GL	PCT	GB
          Hanwha	49	33	2	60	0.598	0.0
              LG	46	37	2	59	0.554	3.5
           Lotte	46	37	3	58	0.554	3.5
             KIA	45	37	3	59	0.549	4.0
             SSG	42	39	3	60	0.519	6.5
              KT	43	40	3	58	0.518	6.5
         Samsung	43	41	1	59	0.512	7.0
              NC	37	40	5	62	0.481	9.5
          Doosan	34	48	3	59	0.415	15.0
          Kiwoom	26	59	3	56	0.306	24.5

The next two tables show, respectively, how many of their remaining games each team wins and ties against each of the other teams in the scenario:

					Scenario Additional Wins Against
Team	Doosan	Hanwha	KIA	Kiwoom	KT	LG	Lotte	NC	Samsung	SSG	Wins
Doosan	-	0	7	0	4	8	5	7	0	9	40
Hanwha	7	-	8	6	8	6	6	4	0	7	52
KIA	0	0	-	4	2	8	7	9	0	6	36
Kiwoom	6	0	0	-	0	7	7	7	0	7	34
KT	0	0	0	4	-	9	4	8	0	8	33
LG	0	0	0	0	0	-	8	5	0	0	13
Lotte	0	0	0	0	0	0	-	8	0	0	8
NC	0	0	0	0	0	0	0	-	1	7	8
Samsung	4	8	6	8	9	4	6	6	-	7	58
SSG	0	0	0	0	0	2	5	0	0	-	7
-----------------------------------------------------------------------------------
Losses	17	8	21	22	23	44	48	54	1	51

					Scenario Additional Draws (Ties) With
Team	Doosan	Hanwha	KIA	Kiwoom	KT	LG	Lotte	NC	Samsung	SSG	Total
Doosan	-	0	0	0	1	0	2	2	0	0	2
Hanwha	0	-	0	0	0	1	0	1	0	0	0
KIA	0	0	-	2	2	0	0	0	0	1	2
Kiwoom	0	0	2	-	0	0	0	1	0	0	0
KT	1	0	2	0	-	0	2	0	0	0	2
LG	0	1	0	0	0	-	1	0	0	2	2
Lotte	2	0	0	0	2	1	-	0	0	0	2
NC	2	1	0	1	0	0	0	-	0	1	0
Samsung	0	0	0	0	0	0	0	0	-	1	0
SSG	0	0	1	0	0	2	0	1	1	-	2
-----------------------------------------------------------------------------------
Total	2	0	2	0	2	2	2	0	0	2

The next two tables show, respectively, how many total games each team wins and ties against each of the other teams in the scenario:

					Scenario Total Wins Against
Team	Doosan	Hanwha	KIA	Kiwoom	KT	LG	Lotte	NC	Samsung	SSG	Wins
Doosan	-	4	9	7	8	12	9	9	5	11	74
Hanwha	12	-	13	15	13	10	10	11	5	12	101
KIA	7	3	-	10	9	12	13	13	3	11	81
Kiwoom	9	1	4	-	3	10	9	9	3	12	60
KT	7	3	5	13	-	13	8	11	5	11	76
LG	4	5	4	6	3	-	12	11	6	8	59
Lotte	5	6	3	7	6	3	-	12	7	5	54
NC	5	4	3	6	5	5	4	-	4	9	45
Samsung	11	11	13	13	11	10	9	12	-	11	101
SSG	5	4	4	4	5	6	11	6	4	-	49
-----------------------------------------------------------------------------------
Losses	65	41	58	81	63	81	85	94	42	90

					Scenario Total Draws (Ties) With
Team	Doosan	Hanwha	KIA	Kiwoom	KT	LG	Lotte	NC	Samsung	SSG	Total
Doosan	-	0	0	0	1	0	2	2	0	0	5
Hanwha	0	-	0	0	0	1	0	1	0	0	2
KIA	0	0	-	2	2	0	0	0	0	1	5
Kiwoom	0	0	2	-	0	0	0	1	0	0	3
KT	1	0	2	0	-	0	2	0	0	0	5
LG	0	1	0	0	0	-	1	0	0	2	4
Lotte	2	0	0	0	2	1	-	0	0	0	5
NC	2	1	0	1	0	0	0	-	0	1	5
Samsung	0	0	0	0	0	0	0	0	-	1	1
SSG	0	0	1	0	0	2	0	1	1	-	5
-----------------------------------------------------------------------------------
Total	5	2	5	3	5	4	5	5	1	5